Course Content
DoD Manual 4145.26 (2008) – Chapter 4: Hazard Classification and Storage Compatibility Systems
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73 Topics
70 Quizzes
C4.1. Hazard Classification
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Basic Structure of the System
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C4.1.1.1. HD 1.1 – Mass-explosion
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Definition of HD 1.1
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C4.1.1.2. HD 1.2 – Non-mass explosion, fragment producing
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Primary Hazard of HD 1.2
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C4.1.1.2.1. HD 1.2.1
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Benchmark Item Role
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C4.1.1.2.2. HD 1.2.2
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Benchmark Role
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C4.1.1.2.3. HD 1.2.3
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Assignment Criteria
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C4.1.1.3. HD 1.3
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Primary Hazard of HD 1.3
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C4.1.1.4. HD 1.4
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Primary Hazard of HD 1.4
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C4.1.1.5. HD 1.5
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Definition of HD 1.5
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C4.1.1.6. HD 1.6
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Definition of HD 1.6
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C4.1.2. In-Process Hazard Considerations
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Contractor Responsibility
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C4.1.2. In-Process Hazard Considerations – Examples and Detailed Analysis Guidance
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Packaged vs. Unpackaged HD 1.1 Materials
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Extended Lesson: C4.1.2. In-Process Hazard Considerations – Testing Requirements per TB 700-2 and ETUG
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TB 700-2 Test Series Overview
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The criticality of C4.1.2 (In-Process Hazard Considerations)
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Broader Safety Role
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Detailed examples of in-process analysis
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C4.2. STORAGE COMPATIBILITY C4.2.1. Storage of AE is based on the DoD hazard classification and compatibility requirements of this chapter.
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Basis of Storage Compatibility
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C4.2.2. Compatibility groups (CGs) and hazard classification for DoD AE items and materials are listed in the Joint Hazard Classification System (JHCS). (See Reference (i).)
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HCSDS Role
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C4.2.3. Compatibility and hazard classification information relating to other hazardous materials (including AE) not contained within the JHCS can be derived from references such as:
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C4.2.3.1. Parts 100-199 of Reference (g)
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Definition of Reference (g)
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C4.2.3.2. NFPA Manual 491M.5 (Reference (j))
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Current Availability
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NFPA 495, Explosive Materials Code (often cross-referenced in DoD explosives safety contexts, including related DoD manuals and contractor guidance).
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Relation to DoD Standards
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C4.2.3.3. Data sheets developed by the National Safety Council
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Current Relevance
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C4.2.3.4. Data sheets developed by the Chemical Manufacturers Association
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Organization Evolution
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C4.2.4. Storage and compatibility principles are:
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Primary Storage Goal
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Lesson: C4.2.4.1. Balancing Safety and Practicality in AE Storage
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Implication for Contractors
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C4.2.4.2. Prohibition on Mixed Storage with Dissimilar Hazards and Special Rules for Non-Class 1 Materials Course Content
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Prohibited Mixed Storage
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C4.2.4.3. Mixing Based on Compatibility (CG), Not Hazard Classification (HD)
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Role of HD vs. CG in Mixing
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C4.2.4.4. Conditional Mixing for Safe Operations and Storage Efficiency
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Condition for Mixing
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C4.2.4.5. Definition of “With Its Own Means of Initiation” and “Without Its Own Means of Initiation”
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Definition of “With Its Own Means of Initiation”
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Definition of “Without Its Own Means of Initiation”
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C4.2.4.6. AE compatibility considerations
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Effect Magnitude
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C4.2.4.6.1. Intra-Group Compatibility and Exceptions for CG K and L Course Content
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Role of Table C4.T1
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C4.2.4.6.2. Isolation of Substandard, Damaged, Suspect, or High-Risk AE
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Trigger for Isolation
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C4.2.4.7. Overview of the 13 Compatibility Groups (CGs)
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Number of Compatibility Groups
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C4.2.4.7.1. Compatibility Group A – Initiating (Primary) Explosives
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Definition of Group A
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C4.2.4.7.2. Compatibility Group B – Detonators and Similar Initiating Devices (Limited Protection)
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Definition of Group B
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C4.2.4.7.3. Compatibility Group C – Bulk Propellants, Propelling Charges, and Propellant-Containing Devices
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Definition of Group C
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C4.2.4.7.4. Compatibility Group D – Bulk High Explosives and HE-Containing AE (Without Initiation or Propelling Charge)
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Definition of Group D
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C4.2.4.7.5. Compatibility Group E – AE with HE and Solid Propelling Charge (Without Initiation)
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Definition of Group E
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C4.2.4.7.6. Compatibility Group F – HE Ammunition or Devices with Initiation (Fuzed/Initiated)
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Definition of Group F
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C4.2.4.7.7. Compatibility Group G – Pyrotechnics, Illuminating, Incendiary, Smoke, and Tear-Producing Munitions (Non-Special)
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Definition of Group G
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C4.2.4.7.8. Compatibility Group H – AE with Explosives and White Phosphorus or Pyrophoric Materials
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Definition of Group H
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C4.2.4.7.9. Compatibility Group J – AE Containing Flammable Liquids or Gels (Non-Spontaneously Reactive)
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Definition of Group J
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C4.2.4.7.10. Compatibility Group K – AE Containing Explosives and Toxic Chemical Agents
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Definition of Group K
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C4.2.4.7.11. Compatibility Group L – Special Risk / Miscellaneous AE Requiring Isolation
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Compatibility Group L is assigned to
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C4.2.4.7.12. Compatibility Group N – AE Containing Only Extremely Insensitive Detonating Substances (EIDS)
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Definition of Group N
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C4.2.4.7.13. Compatibility Group S – AE Presenting No Significant Hazard
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Definition of Group S
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C4.2.4.8. Sensitivity Groups (SGs) for HD 1.1 and HD 1.2 AE with Substantial Dividing Walls
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Meaning of “D” Suffix
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C4.2.4.8.1. Overview of the Five Sensitivity Groups (SGs)
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Source of SG Assignment
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C4.2.4.8.1.1. Sensitivity Group 2 (SG 2) – Non-Robust or Thin-Skinned AE
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Implication of SG 2
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C4.2.4.8.1.2. Sensitivity Group 1 (SG 1) – Robust or Thick-Skinned AE
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Sensitivity Position
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C4.2.4.8.1.2.1. SG 1 Criterion 1 – Ratio of Explosive Weight to Empty Case Weight < 1
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SG 1 Criterion 1
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C4.2.4.8.1.2.2. SG 1 Criterion 2 – Minimum Case Thickness > 0.4 inches (1 cm)
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SG 1 Criterion 2
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C4.2.4.8.1.2.3. SG 1 Criterion 3 – Ratio of Case Thickness to NEWQD^{1/3} > 0.05 in/lb^{1/3} [0.165 cm/kg^{1/3}]
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SG 1 Criterion 3
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C4.2.4.8.1.3. Sensitivity Group 3 (SG 3) – Fragmenting AE
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Typical SG 3 Items
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C4.2.4.8.1.4. Sensitivity Group 4 (SG 4) – Cluster Bombs and Dispenser Munitions
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Typical SG 4 Items
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C4.2.4.8.1.5. Sensitivity Group 5 (SG 5) – Other AE (Low or Unproven Propagation Risk)
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SG 5 as Default
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C4.2.4.8.2. Changing an Item’s Sensitivity Group (SG) via Item-Specific Testing or Analysis
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Purpose of C4.2.4.8.2
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C4.2.4.9. Mixed Storage
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Mixed Storage
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C4.2.4.9.1. Rules for Mixing Compatibility Groups (CGs) and Packaging Requirements
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Mixing Permission Source
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C4.2.4.9.2. Limited Mixed Storage for CGs C, D, E, F, G, J, and S (≤ 1000 lb Net Explosives)
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Eligible CGs
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C4.2.4.9.3. Unlimited Mixed Storage for HD 1.4 Items in CG C, G, or S Course Content
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Eligible Items for Unlimited Mixing
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Full Textual Representation of Table C4.T1
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Note 1 to Table C4.T1 – Meaning of the “X” Marking
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Meaning of “X”
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Note 2 to Table C4.T1 – Meaning of the “Z” Marking and Limited Relaxations
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Meaning of “Z”
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Note 3 to Table C4.T1 – Storage of Separately Packaged Components of Complete Rounds
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Compatibility Treatment
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Note 4 to Table C4.T1 – Special Storage Requirements for Group K Course Content
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Group K Storage from Other Groups
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Note 5 to Table C4.T1 – Storage of Ammunition Items Without Explosives but Containing Other Hazard-Class Substances
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Scope of Note 5
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Note 6 to Table C4.T1 – Storage of “Practice” Ammunition with Fully Loaded Ammunition
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Authorization Requirement
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Note 7 to Table C4.T1 – Additional Component-Level Authorization for Mixing CGs B, H, and N
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Quantity Guideline
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Note 8 to Table C4.T1 – Packaging and Container Opening Rules for Mixed Storage
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Packaging Requirement
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Note 9 to Table C4.T1 – Segregation Requirement for Group B or F When Using “Z” Mixing
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When Note 9 Applies
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Note 10 to Table C4.T1 – Special Rules for Mixing HD 1.6 (Group N) Items
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Rule for Dissimilar HD 1.6 Mixing
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End of Course Narrative: The Critical Importance of Contractual Compliance with DoD Manual 4145.26, Chapter 4
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Final Quiz
Final Quiz – Chapter 4 – HAZARD CLASSIFICATION AND STORAGE COMPATIBILITY SYSTEMS
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